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Q. What is empirical formula of an oxide of iron which has $69.9 \%$ iron and $30 \%$ oxygen by mass?

Solution:

$\%$ of mass Atomic mass Relative no.of moles Simple ratio Simple whole no
Iron $Fe$ $69.9$ $55.85$ $69.9 / 55.85=1.25$ $\frac{1.25}{1.25}=1$ $2$
Oxygen $O$ $30.1$ $16.0$ $30.1 / 16=1.88$ $\frac{1.88}{1.25}=1.5$ $3$

Formula $= Fe _{2} O _{3}$