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Q. Wavelengths belonging to Balmer series lying in the range of $450nm$ to $750nm$ were used to eject photoelectrons from a metal surface whose work function is $2.0eV$ . The maximum kinetic energy of the emitted photoelectrons is $a$ . Write value of $100a$ . (Take $hc=1242eVnm$ .)

NTA AbhyasNTA Abhyas 2022

Solution:

Wavelengths corresponding to minimum wavelength (λmin ) or maximum energy will emit photoelectrons having kinetic energy which is maximum. (λmin) belonging to Balmer series and Lying in the given range (450 nm to 750 nm) corresponds to transition from (n = 4 to n = 2). Here,
$E_{4}=-\frac{1 3 . 6}{\left(4\right)^{2}}=-0.85\text{eV}$
$\left(\text{and} E\right)_{2}=-\frac{1 3 . 6}{\left(2\right)^{2}}=-3.4\text{eV}$
$\therefore \Delta E =E ⁡_{4}-E ⁡_{2}=2.55\text{eV}$
$K _{\text{max}}=\text{Energy of photon}-\text{work function}=2.55-2.0=0.55\text{eV=a}$
Hence, $100a=55$