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Q. Two identical breakers A and B contain equal volumes of two different liquids at $60^{\circ}C$ each and left to cool down. Liquid in A has density of $8 \times 10^2 \; kg/m^3$ and sp ecific heat o f 2000 J $kg^{-1} \; K^{-1}$ while liquid in B has density o f 103 kg m-3 and sp ecific heat o f 4000 J $kg^{-1} K^{-1}$. Which of the following best describes their temperature versus time graph schematically? (assume the emissivity of both the beakers to be the same)

JEE MainJEE Main 2019Thermal Properties of Matter

Solution:

$-ms \frac{dT}{dt} =e\sigma A \left(T^{4} -T_{0}^{4}\right) $
$ -\frac{dT}{dt} = \frac{e\sigma A}{ms} \left(T^{4}-T^{4}_{0}\right) $
$- \frac{dT}{dt} = \frac{4e\sigma AT_{0}^{3}}{ms} \left(\Delta T\right) $
$ T =T_{0} + \left(T_{i} - T_{0}\right)e^{-kt} k = \frac{4e\sigma AT_{0}^{3}}{ms} $
where $ k = \frac{4e\sigma AT_{0}^{3}}{\rho vs} $
$\left|\frac{dT}{dt}\right| \propto k $
$\therefore \left|\frac{dT}{dt}\right|\propto \frac{1}{\rho s} $
$ \rho_{A}S_{A} =2000\times8\times10^{2} =16 \times10^{5} $
$ \rho_{B}S_{B} =4000 \times10^{3} = 4 \times10^{6} $
$ \rho_{A}S_{A} < \rho_{B}S_{B} $
$ \left|\frac{dT}{dt}\right|_{A} > \left|\frac{dT}{dt}\right|_{B} $

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