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  4. Total number of moles of AgCl precipitated on addition of excess of AgNO 3 to one mole each of the following complexes [ Co ( NH 3)4 Cl 2] Cl, [ Ni ( H 2 O )6] Cl 2,[ Pt ( NH 3)2 Cl 2] and [ Pd ( NH 3)4] Cl 2 is

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Q. Total number of moles of $AgCl$ precipitated on addition of excess of $AgNO _3$ to one mole each of the following complexes $\left[ Co \left( NH _3\right)_4 Cl _2\right] Cl$, $\left[ Ni \left( H _2 O \right)_6\right] Cl _2,\left[ Pt \left( NH _3\right)_2 Cl _2\right]$ and $\left[ Pd \left( NH _3\right)_4\right] Cl _2$ is

JEE MainJEE Main 2023Coordination Compounds

Solution:

$\left[ Co \left( NH _3\right)_4 Cl _2\right] Cl \Rightarrow$ Gives 1 mole $AgCl$
$\left[ Ni \left( H _2 O \right)_6\right] Cl _2 \Rightarrow$ Gives 2 moles $AgCl$
$\left[ Pt \left( NH _3\right)_2 Cl _2\right] \Rightarrow$ Gives No $AgCl$
$\left[ Pd \left( NH _3\right)_4\right] Cl _2 \Rightarrow$ Gives 2 moles $AgCl$
Total number of moles of $AgCl =5$ mole.