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Q. The work function of the metal $A$ is equal to the ionization energy of the hydrogen atom in the first excited state. The work function of the metal $B$ is equal to the ionization energy of $He^{+} \, $ ion in the second orbit. Photons of the same energy $E$ are incident on both $A$ and $B$ . The maximum kinetic energy of photoelectrons emitted from $A$ is twice that of photoelectrons emitted from $B$ . Value of $E$ ( in $eV$ ) is

NTA AbhyasNTA Abhyas 2020

Solution:

$E_{n}=13.6\frac{Z^{2}}{n^{2}}$
$W_{A}$ = ionization energy of an electron in 2nd orbit of the hydrogen atom $=3.4eV$
$W_{B}$ = ionization energy of an electron in 2nd orbit of He+ ion
$=13.6eV$ .
Now, given that
$K_{\text{A}}=2K_{\text{B}}$
or $\left(E - W_{\text{A}}\right)=2\left(E - W_{\text{B}}\right)$
$\therefore \textit{E}=2\textit{W}_{\text{B}}-\textit{W}_{\text{A}}=\text{23.8 eV}$