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Chemistry
The wave number of last line of Lyman series of hydrogen spectrum is 109674 cm -1. The wave number of H α line in Balmer series of He + is
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Q. The wave number of last line of Lyman series of hydrogen spectrum is $109674 cm ^{-1}$. The wave number of $H _{\alpha}$ line in Balmer series of $He ^{+}$ is
Structure of Atom
A
$438696 \,cm ^{-1}$
17%
B
$109674 \,cm ^{-1}$
38%
C
$30465\, cm ^{-1}$
24%
D
$60930\, cm ^{-1}$
21%
Solution:
$\bar{v}=R Z^{2}\left(\frac{1}{n_{1}^{2}}-\frac{1}{n_{2}^{2}}\right)$
For the last line of Lyman series of $H$ -spectrum,
$Z=1, n_{1}=1$ and $n_{2}=\infty$
For $H _{\alpha}$ line in Balmer series of $He ^{+}, Z=2, n_{1}=2$ and $n_{2}=3$
On putting the values,
$\bar{v}=109674 \times 2^{2}\left(\frac{1}{2^{2}}-\frac{1}{3^{2}}\right)=60930 \,cm ^{-1}$