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Chemistry
The void space in a primitive unit cell is:
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Q. The void space in a primitive unit cell is:
NTA Abhyas
NTA Abhyas 2022
A
48% void space
B
24% void space
C
96% void space
D
50% void space
Solution:
$a = 2r $
Volume of the cube $=a^{3}=\left(2 r\right)^{3}=8r^{3}$
Packing fraction $=\frac{\text{Volume of one atom}}{\text{Volume of the cube}}$
$=\frac{\left(\frac{4}{3} \, \pi r^{3}\right)}{8 r^{3}}=\frac{\pi }{6}=0.52$
Void fraction $= \, 1 \, - \, 0.52 \, = \, 0.48$
Void space $=48 \, \%$