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Q. The unit cell in a body centred cubic lattice is given in the figure. Each sphere has a radius $r$ and the cube has side $'a'.$ What fraction of the total cube volume is empty?

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The Solid State

Solution:

$Z _{ eff }$ of $BCC =2$
Volume occupied by atoms $=2 \times \frac{4}{3} \pi r^{3}$
Volume of unit cell $=a^{3}$
Packing fraction $=\frac{8}{3} \pi \frac{r^{3}}{a^{3}}$
Fraction of empty unit cell $=1-\frac{8}{3} \pi \frac{r^{3}}{a^{3}}$