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Q. The total internal energy of one mole of rigid diatomic gas is

Kinetic Theory

Solution:

A rigid diatomic molecule has $5$ degrees of freedom:
$3$ translational and $2$ rotational.
According to the law of equipartition of energy, the total internal energy of one mole of rigid diatomic gas is
$U=\frac{5}{2} k_{B} T \times N_{A}=\frac{5}{2} R T $
$\left(\because R=k_{B} N_{A}\right)$