Acceleration due to gravity at the center of the earth is zero.
$
\Longrightarrow g =0
$
Time period of a simple pendulum is given by,
$T =2 \pi \sqrt{\frac{1}{ g }}$
$
\Longrightarrow T =2 \pi \sqrt{\frac{1}{0}} \\
\therefore T =\infty
$
So time period at the centre of the earth becomes infinite.