For system of linear equations has no solution,
$\begin{vmatrix}1 & 1 & 1 \\1 & 2 & 3 \\1 & 2 & a\end{vmatrix}=0$
$\Rightarrow 1(2 a-6)-1(a-3)+1(2-2)=0$
$\Rightarrow 2 a-6-a+3=0$
$\Rightarrow a-3=0$
$\Rightarrow a=3$
Now, options (a) and (d) satisfy $a=3$. If $b=10$, then equations (ii) and (iii) become identical and system will have infınite solutions. Hence, $a=3$, $b \neq 10$