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Q. The standard e.m.f of a cell, involving one electron change is found to be $0.591\, V$ at $25^{\circ}C$. The equilibrium constant of the reaction is $(F = 96,500 \,C \,mol^{-1} : R = 8.314\, JK^{-1} \,mol^{-1})$

AIEEEAIEEE 2004

Solution:

$\therefore log \,K_{eq} = \frac{nE^{\circ}}{0.0591} = \frac{1\times0.591}{0.0591}$
$⇒ K_{eq} = 10^{10}$