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Q. The solubility of $ Sb_{2}S_{3} $ , in water is $ 1.0\times 10^{-5} $ $ mol/L $ at $ 298\,\,K $ . What will be its solubility product?

Rajasthan PMTRajasthan PMT 2006

Solution:

$\underset{s\,mol/L}{Sb_2S_3} \ce{<=>} \underset{2s}{2Sb^{3+}} + \underset{3s}{3S^{2-}}$
Solubility product $(K_{sp}) = [Sb^{3+}][S^{2-}]^3$
$=(2 s)^{2}(3 s)^{3}=108 s^{5}$
$=108 \times\left(1.0 \times 10^{-5}\right)^{5}=108 \times 10^{-25}$