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Q. The shortest wavelength of the Brackett series of a hydrogen like atom (atomic number $=Z$ ) is the same as the shortest wavelength of the Balmer series of hydrogen atom. The value of $Z$ is

NTA AbhyasNTA Abhyas 2022

Solution:

Shortest wavelength of Brackett series corresponds to the transition of electron between $n_{1}=4$ and $n_{2}=\in fty$ and the shortest wavelength of Balmer series corresponds to the transition of electron between $n_{1}=2$ and $n_{2}=\in fty$ , So,
$\left(z^{2}\right)\left(\frac{13.6}{16}\right)=\left(\frac{13.6}{4}\right)$
$\therefore \, \, Z^{2}=4$
or $Z=2$