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Q. The rate of reaction
$ CC{{l}_{3}}CHO+NO\xrightarrow[{}]{{}}CHC{{l}_{3}}+NO+CO $ Is equal to rate $ =k[CC{{l}_{3}}CHO][NO] $. If concentration is expressed in $ mol\text{ }{{L}^{-1}}, $ the unit of $ k $ is

ManipalManipal 2012Chemical Kinetics

Solution:

Rate $ =\frac{dx}{dt}=k[CC{{l}_{3}}CHO][NO] $
$ k=\frac{dx}{dt\times [CC{{l}_{3}}CHO][NO]} $
$ =\frac{mol\,{{L}^{-1}}}{{{s}^{-1}}\times mol\,{{L}^{-1}}\times mol\,{{L}^{-1}}} $
$ =L\,mo{{l}^{-1}}{{s}^{-1}} $