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Chemistry
The quantity of CO 2 in 500 mL of soda water when packed under 3.34 bar CO 2 pressure at 298 K in g is
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Q. The quantity of $CO _{2}$ in $500\, mL$ of soda water when packed under $3.34$ bar $CO _{2}$ pressure at $298\, K$ in $g$ is
AP EAMCET
AP EAMCET 2018
A
2.442
B
1.221
C
4.884
D
3.663
Solution:
Given, Quantity of $CO _{2}=500\, mL$
Pressure of $CO _{2}= 3.34$ bar
Temperature $=298\, K$ in Henry's law
$p=K_{ H } X \times(x)$
$X=\frac{p}{K_{ H }}=3.34\, bar =334000\, Pa$
$=\frac{3.34 \times 10^{1}}{1.67 \times 10^{8}}=2.442\, Pa$
But, we have $500\, mL$ of soda water so that
Volume of water $=500\, mL$
Density of water $= 1\, g / mL$
Formula mass $=$ volume $\times$ density we get
$500\, mL$ of water $=500 \,g$ of water
Molar mass of water $=18\, g / mol ^{-1}$
$\frac{500}{18}=27.78$ mole $\mu$ of water
$x=\frac{n_{ CO _{2}}}{n_{ CO _{2}}+n_{ H _{2} O }}$
Value of moles fraction is very small so it is negligible as compared to 1 we get,
$x=\frac{n_{ CO _{2}}}{n_{ H _{2} O }}=2 \times 10^{-7}$
Molar mass of $CO _{2}$ is after calculation $=2.442\, g$