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  4. The properties of carbonyl group <img class=img-fluid question-image alt=Question src=https://cdn.tardigrade.in/q/nta/c-ytiq3wfcnv3z.png /> is suppressed the most in

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Q. The properties of carbonyl group Question is suppressed the most in

NTA AbhyasNTA Abhyas 2020Organic Chemistry – Some Basic Principles and Techniques

Solution:

The resonance structures for RCOG are

Solution

or Solution

Electron-release from G(H, $CH_{3},OCH_{3}$ or $NH_{2}$ ) to O stabilizes Solution by diminishing the electrophilic character of carbonyl carbon. Since degree of delocalization is maximum in case of $-NH_{2}$ , therefore, the properties of Solution is suppressed most in amides $\left(\right.RCONH_{2}\left.\right)$ .