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Q. The $ pH $ value of $ HCl({{10}^{-12}}M) $ is

Punjab PMETPunjab PMET 1999

Solution:

We know that $ {{10}^{-12}}M $ solution of $ HCl $ is very dilute. So concentration of $ H $ ions due to self-ionisation of water cannot be neglected. Therefore, $ {{[{{H}^{+}}]}_{total}}={{H}^{+}}[from\,\,HCl+water] $ $ -\log [1.00001\times {{10}^{-7}}]=7. $ We also know that $ pH=-\log [{{H}^{+}}] $ $ =-\log [1.00001\times {{10}^{-7}}]=7 $