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Chemistry
The pH of ammonium phosphate solution, if pK a of phosphoric acid and pk b of ammonium hydroxide are 5.23 and 4.75 respectively, is
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Q. The $pH$ of ammonium phosphate solution, if $pK _{ a }$ of phosphoric acid and $pk _{ b }$ of ammonium hydroxide are $5.23$ and $4.75$ respectively, is___
JEE Main
JEE Main 2021
Equilibrium
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Solution:
Since $\left( NH _{4}\right)_{3} PO _{4}$ is salt of weak acid $\left( H _{3} PO _{4}\right)$ & weak base $\left( NH _{4} OH \right)$
$pH =7+\frac{1}{2}( pka - pkb )$
$=7+\frac{1}{2}(5.23-4.75)$
$=7.24 \approx 7$