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Q. The percentage of ammonia obtainable, if equilibrium were to be established during the Haber process, is plotted against the operating pressure for two temperatures, $400^{\circ} C$ and $500^{\circ} C$. Which of the following graph correctly represent the process?

Equilibrium

Solution:

$N _{2}( g )+3 H _{2}( g ) \rightleftharpoons 2 NH _{3}( g ) ; \Delta H < 0$

By Le Chatelier principle, higher pressure and lower temperature favour the forward reaction, i.e., higher $\%$ of $NH _{3}$.