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Q. The oxidation state $(n)$ and coordination number $(CN)$ of $Al$ and number of valence electrons around $Al ( N )$ in $Al _{2} Cl _{6}$ are respectively

TS EAMCET 2019

Solution:

Structure of $Al _{2} Cl _{6}$ is

image

Therefore,

(i) Oxidation state $(x)$ of ' $Al $ ' in $Al _{2} Cl _{6} :=2 x-6=0$ or $x=(+) 3$

(ii) Coordination number of $Al$ in $Al _{2} Cl _{6}$ is four $(4)$ , it is bonded to $4$ chlorine atoms in $Al _{2} Cl _{6}$.

(iii) Number of valence electrons around $Al$ in $Al _{2} Cl _{6}=2 \times 4=8$