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Q.
The order of which of the following oxides is arranged according to decreasing basic nature?
Classification of Elements and Periodicity in Properties
Solution:
Applying Fajans’ rule, the lower the charge; the more is ionic and the more is basic and vice versa.
Moreover, small cation, large anion, high charge and presence of $d$ electrons mean more covalent and more acidic.
Therefore, decreasing order of basic nature is
Size $Al^{3+} > Cu^{2+}$ and presence of d electron in $Cu^{2+}$ makes it less basic (or more acidic) than $Al_2O_3$.