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Q. The number of moles of $KMnO_4$ required to oxidise one equivalent of $KI$ in the presence of sulphuric acid is

KVPYKVPY 2014

Solution:

$\overset{+7}{KMnO_{4}}+\overset{-1}{KI}+H_{2}SO_{4}\rightarrow$
$\overset{+2}{Mn}SO_{4}+\overset{0}{I}_{2}+K_{2}SO_{4}+H_{2}O$
Balance factor for $Mn = 5$
Balance factor for $I=1$
Equivalent of $KMnO_4$ = equivalent of $KI$
Number of equivalents = $y \times$ Number of moles
where, $y$ is the balance factor.
$=y_{Mn}\times n_{Mn}=y_{KI}\times n_{KI} $
$=5\times x_{Mn}=1\times1$
$n_{Mn}=\frac{1}{5}$