We are aware that normally rain water has a $pH$ of $5.6$ due to the presence of $H ^{+}$ions formed by the reactions of rain water with carbon dioxide present in the atmosphere.
$ H _2 O ( l )+ CO _2( g ) \leftrightharpoons H _2 CO _3( aq )$
$H _2 CO _3( aq ) \leftrightharpoons H ^{+}( aq )+ HCO _3^{-}( aq ) $