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Q. The molar freezing point constant for water is $1.86^{\circ} C / mol$. If $342\, g$ of cane sugar $\left(C_{12} H_{22} O_{11}\right)$ is dissolved in $1000\, g$ of water, the solution will freeze at:

Haryana PMTHaryana PMT 2006

Solution:

Molality of cane sugar solution $=\frac{342}{342 \times 1}=1\, m$
We know that, $\Delta T_{f}=K_{f} . m=1.86 \times 1 m=1.86^{o}$
Hence, freezing point of solution
$=0.00-(1.86)=-1.86^{\circ} C$