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Q. The methods by which aniline could be prepared is/are
(i) Reduction of nitriles
(ii) Gabriel phthalimide synthesis
(iii) Reduction of amides
(iv) Hoffmann’s bromamide reaction

J & K CETJ & K CET 2016Amines

Solution:

Reduction of nitriles, Gabriel phthalimide synthesis and reduction of amides give only aliphatic or aryl alkyl amines.
Hoffmann’s bromamide reaction gives aniline
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