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Q. The heat of solution of one mole of $Na_{2}SO_{4}.10H_{2}O$ is -78.7 kJ, and that of dehydration, -81.6 kJ. The heat of solution (kJ) of anhydrous sodium sulphate is

NTA AbhyasNTA Abhyas 2020Thermodynamics

Solution:

Solution

From Hess's law, $\text{Q} = - \left(- 81.6 \, \text{kJ}\right) + \left(- 78.7 \, \text{kJ}\right)$

$= 81.6 \, \text{kJ} - 78.7 \, \text{kJ} = + 2.9 \, \text{kJ}$