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Q. The heat capacity of liquid water at constant pressure, $C_{P}$ is $18 \,cal \,deg^{-1}\, mol^{-1}$ The value of heat capacity of water at constant volume, $C_{v}$ is approximately

Thermodynamics

Solution:

$C_{p}=C_{v}=2\,cal\,deg^{-1}\,mol^{-1}$
$C_{V}=C_{P}-2 =18-2=16\,cal\,deg^{-1}\,mol^{-1}$