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Q. The freezing point of one molal NaCl solution assuming NaCl to be 100% dissociated in water(molal depression constant = 1.86) :

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Solution:

For $NaCl \,i=2$
$\Delta T_{f}=2 K_{f} m$
$=2 \times 1.86 \times 1=3.72$
$T_{s}=T-\Delta T_{f}$
$=0-3.72=-3.72{ }^{\circ} C$