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Q. The freezing point of equimolal aqueous solutions will be highest for

IIT JEEIIT JEE 1990Solutions

Solution:

$C_6H_5NH_3CI : i = 2$ ;
$Ca(NO_3)_2 : i = 3$
$La(NO_3)_3: i=4;$
$C_6H_{12}O_6 : i=1$
Lower the value of $i$, smaller will be the depression in freezing point, higher will be the freezing temperature, if molalities are equal. Hence, glucose solution will have highest freezing temperature.