Hatch and Slack cycle is present in $ {{C}_{4}} $ plants in which initial fixation of carbon dioxide $ (C{{O}_{2}}) $ occurs in mesophyll cells phosphoenol pyruvate (PEP) is the primary acceptor of $ C{{O}_{2}} $ which combines to $ C{{O}_{2}} $ form four carbon compounds oxaloacetic acid as a result of carboxylation $ PEP+C{{O}_{2}}+{{H}_{2}}O\xrightarrow[\begin{smallmatrix} Carboxylase \\ Oxalso-\,acetic\,acid \end{smallmatrix}]{PEP} $