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Q. The equilibrium $ SO_2Cl_2 \, ( g) \rightleftharpoons SO_2 \, ( g) + Cl_2 \, ( g) $ is attained at $ 25^{\circ}C$ in a closed container and an inert gas, helium is introduced. Which of the following statements are correct ?

IIT JEEIIT JEE 1981Equilibrium

Solution:

$ SO_2Cl_2 \, ( g) \rightleftharpoons SO_2 \, ( g) + Cl_2 \, ( g) $ .
Adding inert gas at constant volume will not affect partial pressure of reactant or products, hence will not affect equilibrium amount o f either reactant or products.