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Q. The enthalpy of solution of sodium chloride is $4\, kJ\, mol^{-1}$ and its enthalpy of hydration of ions is $ -784\, kJ \,mol^{-1}$. What will be the lattice enthalpy of sodium chloride?

Thermodynamics

Solution:

$\Delta H_{sol} = \Delta H_{lattice}+\Delta H_{hyd}$
$4 = \Delta H_{lattice} + \left(-784\right)$
$\Delta H_{lattice} = 4-\left(-784\right)$
$= + 788\,kJ\,mol^{-1}$