Question Error Report

Thank you for reporting, we will resolve it shortly

Back to Question

Q. The correct order of basic strength of the following areChemistry Question Image

UPSEEUPSEE 2013Amines

Solution:

As it is known that electron-releasing group increases the basic strength and electron withdrawing group decreases the basic strength of $- NH _{2}$ group.

As in image

group is planked between two electron withdrawing groups, compound (1) is least basic among all. In compound $(2),- NH -$ is attached with one electron withdrawing group $- CO -$ and one electron releasing group $- CH _{3}$, it is a bit basic than compound

(1). In compound (4)- COCH $_{3}$, group is attached to aniline ring, not directly with $- NH _{2}$ group.

Hence it is more basic than compound (2). Compound (3) is most basic among all compounds since in it, $- NH _{2}$ is atached to only one electron releasing group $\left(- CH _{2}-\right)$. Thus, the correct order of basic strength will be

$3>\,4>\,2>\,1$