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Chemistry
The correct decreasing order of pKa is
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Q. The correct decreasing order of $pK_a$ is
AIIMS
AIIMS 2011
Alcohols Phenols and Ethers
A
$II > I > IV > III $
42%
B
IV > II > III > I
15%
C
III > II > IV > I
27%
D
IV > I > II > III
16%
Solution:
Weaker acids have higher $pk_{a}-OCH_3$ at meta-position exerts only $-I $ effect, hence increases the acidity.
$-I$ effect order : - $NO_2 >\, -OCH_3 >\, -Cl$
$-CH_3$ has $+I$ effect