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Q. The correct decreasing order of $pK_a$ isChemistry Question Image

AIIMSAIIMS 2011Alcohols Phenols and Ethers

Solution:

Weaker acids have higher $pk_{a}-OCH_3$ at meta-position exerts only $-I $ effect, hence increases the acidity.

$-I$ effect order : - $NO_2 >\, -OCH_3 >\, -Cl$

$-CH_3$ has $+I$ effect