The $F ^{\ominus}$ ions make the enamel on teeth much harder by converting hydroxyapatite, $\left[3\left( Ca _{3}\left( PO _{4}\right)_{2}\right] \cdot Ca ( OH )_{2}\right]$, the enamel on the surface of the teeth into much harder fluroappatite. $\left[3 Ca _{3}\left( PO _{4}\right)_{2} . CaF _{2}\right]$