$\left(i\right)H_{2}O_{2}$ act as oxidising agent as well as reducing agent depending on condition.
(ii) $H_{2}SO_{3}$ act as oxidising agent as well as reducing agent depending on condition.
(iii) $HNO_{2}$ act as oxidising agent as well as reducing agent depending on condition.
(iv) $H_{3}PO_{4}$ can not act both as oxidising and reducing agent.
$H_{3}PO_{4}$ can act as only oxidising agent.
$H_{3}PO_{4} {\rightleftharpoons} 3H^{+}+PO_{4}^{3-}$