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Chemistry
The bond length of H2+, H2- and H2 are in the following order
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Q. The bond length of $ H_2^+, H_2^- $ and $ H_2 $ are in the following order
UPSEE
UPSEE 2010
A
$ H_2^ + > H_2 > H_2^ - $
B
$ H_2 > H_2^+ > H_2^- $
C
$ H_2^- > H_2 > H_2^+ $
D
$ H_2^- > H_2^+ > H_2 $
Solution:
$H _{2}^{+}(2-1=1)=\sigma 1 s^{1}$
$BO =\frac{1-0}{2}=0.5$
$H _{2}^{-}(2+1=3)=\sigma 1 s^{2}, \overset{*} {{\sigma}} 1 s^{1} $
$BO =\frac{2-1}{2}=0.5$
$H _{2}(2)=\sigma 1 s^{2}$
$BO =\frac{2-0}{2}=1$
$\because$ The order of bond order is
$H _{2}> H _{2}^{+}> H _{2}^{-}$
Thus, the order of bond length is
$H _{2}^{-}> H _{2}^{+}> H _{2}$