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Chemistry
The best method for the preparation of 2,2 -dimethyl-butane is via the reaction of
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Q. The best method for the preparation of $2,2$ -dimethyl-butane is via the reaction of
WBJEE
WBJEE 2013
Hydrocarbons
A
$Me_3CBr$ and $MeCH_2Br$ in $Na$/ether
52%
B
$(Me_3C)_2CuLi$ and $MeCH_2Br$
18%
C
$(MeCH_2)_2CuLI$ and $Me_3CBr$
21%
D
$Me_3CMgI$ and $MeCH_2I$
9%
Solution:
$2,2$ - dimethyl butane is prepared from Corey House alkane synthesis.
$(Ma_{3}C)_{2} CuLi + MeCH_{2} Br \xrightarrow{SN^{2}}$
$me_{3}C -CH_{2}CH_{3}+\overset{Br}{Me_{3}C}\,\,\, CuLi$