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Q. The atomic numbers of vanadium (V), chromium (Cr), manganese (Mn) and iron (Fe) are respectively 23,24,25 and $26$ Which one of these may be expected to have the highest second ionization enthalpy?

AIEEEAIEEE 2003

Solution:

(by first IP)

This is stable EC hence formation of $Cr ^{2+}$ by second IP requires maximum enthalpy