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Q. Statement 1: Sodium bicarbonate generally precipitates normal carbonate from magnesium chloride solution
Statement 2: Sodium carbonate generally precipitates basic carbonate from magnesium chloride solution

The s-Block Elements

Solution:

Statement 1: $MgCl_{2} +NaHCO_{3}\to MgCO_{3}+2NaCl+CO_{2}+H_{2}O$
Statement 2: $MgCl_{2}+2Na_{2}CO_{3}+H_{2}O \to MgCO_{3}\,Mg(OH)_{2}+4NaCl+CO_{2}$