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Q. Statement 1: Permanganate titrations in presence of hydrochloric acid are unsatisfactory
Statement 2: Hydrochloric acid is oxidised to chlorine by $MnO^{-}_4$

The d-and f-Block Elements

Solution:

$MnO^{-}_4$ ion reacts with $Cl^{-}$ to produce $Cl_2$ and $Mn^{2+.}$