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Q. Statement 1 : $NO_2$ is readily dimerised to $N_2O_4$.
Statement 2 : $NO_2$ has one unpaired electron and two such electrons with opposite spin in two $NO_2$ molecules form bond between two $N$-atoms readily.

Chemical Bonding and Molecular Structure

Solution:

Since the process does not require any rearrangement and thus energy of activation for dimerisation of $NO_2^-$ is low.