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Q. Statement 1: Ebullioscopy or cryoscopy cannot be used for the determination of molar mass of polymers
Statement 2: High molar mass solute leads to very low value of $\Delta\,T_{b}$ or $\Delta\,T_{f}$

Solutions

Solution:

If molar mass is low, $\Delta\,T_{b}$ or $\Delta\,T_{f}$ { being low cannot be read out accurately. A little error in measurement of $\Delta\,T_{b}$ will cause abnormal values of mol. wt