Q.
Statement-1 : Aniline on reaction with $NaNO_2/HCl$ at $0^\circ C$ followed by coupling with $\beta$-naphthol gives a dark blue coloured precipitate.
Statement-2 : The colour of the compound formed in the reaction of aniline with $NaNO_2/HCl$ at $0°C$ followed by coupling with p-naphthol is due to the extended conjugation.
IIT JEEIIT JEE 2008Amines
Solution:
$C_6H_5NH_2 + NaNO_2/HCl\xrightarrow {0^{\circ}C} C_6H_5N^+_2 Cl^-$
