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Chemistry
Some pairs of ions are given below. In which pair, first ion is more stable than second ion ?
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Q. Some pairs of ions are given below. In which pair, first ion is more stable than second ion ?
UPSEE
UPSEE 2017
Organic Chemistry – Some Basic Principles and Techniques
A
$H _{3} C - \overset{\oplus}{C} H - CH _{3}$ and $- \overset{\oplus}{C} H -\ddot{ O } CH _{3}$
22%
B
$H_3C - CH_2 - \overset{ \oplus} {C} H - CH_3$ and $H_2C - CH_2 - CH - \overset{ \oplus}{ C}H_2$
34%
C
22%
D
22%
Solution:
For carb-cations :
(i) order of stability $=3^{\circ}>2^{\circ}>1^{\circ} .$
(ii) (+) ve carbon centre in conjugation is more stable.
iii) Substituted carbcations is more stable. Thus, option (a) is the correct choice.