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Q. Some amount of dichloromethane $\left( CH _2 Cl _2\right)$ is added to $671.141 \,mL$ of chloroform $\left( CHCl _3\right)$ to prepare $2.6 \times 10^{-3} M$ solution of $CH _2 \,Cl _2( DCM )$. The concentration of DCM is____$ ppm $(by mass).
Given: Atomic mass : $C =12 ; H : 1 ; Cl =35.5$ density of $CHCl _3=1.49\, g \,cm ^{-3}$

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Solution:

Molarity $=\frac{\text { mole }}{\text { volume }} $
$2.6 \times 10^{-3} =\frac{ x / 85}{0.67141} $
$x =0.148 \,g$
conc. Fo DCM in ppm $=\frac{0.148}{1.49 \times 671.141} \times 10^6 $
$ =148 \,ppm $