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Q. Solubility product of $Ba ( OH )_{2}$ and $Al ( OH )_{3}$ are $1.8 \times 10^{-10}$ and $2.4 \times 10^{-20}$ respectively. If both $Al ^{+3}$ and $Ba ^{+2}$ ions are present in a solution, which one will be ppt on addition of Ammonium hydroxide solution

Equilibrium

Solution:

Compound having low $K _{ sp }$ precipitated first