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Q. Solubility of a $ M_2 S $ type salt is $ 3.5 \times 10^{-6} $ ,then find out its solubility product

AIPMTAIPMT 2001Equilibrium

Solution:

Solubility of $M_{2} S$ salt is $3.5 \times 10^{-6} M$
$\underset{3.5 \times 10^{-6} M}{M _{2} S } \rightleftharpoons \underset{2 \times 3.5 \times 10^{-6} M}{2 M ^{+}}+ \underset{3.5 \times 10^{-6} M}{S^{2-}}$
$\therefore$ ( on $100\%$ ionisation)
$\therefore K_{ sp }$ (Solubility product of $M_{2} S$ )
$=\left[M^{+}\right]^{2}\left[S^{2-}\right]$
$=\left(7.0 \times 10^{-6}\right)^{2}\left(3.5 \times 10^{-6}\right)$
$=171.5 \times 10^{-18}=1.71 \times 10^{-16}$