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Chemistry
Solid PCl5 exists as:
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Q. Solid $ PC{{l}_{5}} $ exists as:
JIPMER
JIPMER 2002
The p-Block Elements - Part2
A
$ PC{{l}_{5}} $
16%
B
$ PCl_{4}^{+} $
11%
C
$ PCl_{6}^{-} $
6%
D
$ PCl_{4}^{+} $ and $ PCl_{6}^{-} $
67%
Solution:
Solid $ PC{{l}_{5}} $ exists as $ {{[PC{{l}_{4}}]}^{+}}{{[PC{{l}_{6}}]}^{-}}.\,\,{{[PC{{l}_{4}}]}^{+}} $ has tetrahedral and $ {{[PC{{l}_{6}}]}^{-}} $ has octahedral geometry.